Synthesis And Characterization of Sulfur Donor Ligand (xanthate) Complexe with Manganese (ll), Iron (ll), Cobalt (ll), Nikel (ll), Copper (ll), And Zinc (ll) And Thier Adduct with Nitrogen Base Ligande
نویسندگان
چکیده
New complexes and adducts of xanthate the general formula [M(cyclopentyl xant.)2] xant.)2.nL] Where M= Mn(ΙΙ) Fe(ΙΙ), Co(ΙΙ), Ni(ΙΙ), Cu(ΙΙ) Zn(ΙΙ), (cyclopentyl xant.)2=[Cyclopentyl ligand], n=2 L= Pyridine, 3-acetyl pyridine & Quinoline n=1, ethylenediamine, (1,10)-phenanthroline, prepared has been evaluated based on their magnetic, electrical, physical characteristics. And spectral methods 1H-NMR xant.) ligand, Based effective magnetic moment electronic spectra, structures kind indicate a tetrahedral geometry whereas an octahedral geometry. The density functional theory (DFT) calculations ligands were performed by DFT/B3LYP/6-311++G(d,p) method to obtain optimized molecular geometry, highest occupied orbital (HOMO), lowest unoccupied (LUMO), properties , thermodynamic parameters are done for four coordinates
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ژورنال
عنوان ژورنال: ???? ????? ????
سال: 2022
ISSN: ['1812-7568', '2521-4861']
DOI: https://doi.org/10.26682/sjuod.2022.25.2.23